Research Article | Open Access
Volume 8 | Issue 1 | Year 2021 | Article Id. IJAC-V8I1P103 | DOI : https://doi.org/10.14445/23939133/IJAC-V8I1P103Spectrophotometric Determination of Vanadium (V) using 2-Furohydroxamic Acid as A New Analytical Reagent
Vinita Rajeev, Surendra K Rajput
Citation :
Vinita Rajeev, Surendra K Rajput, "Spectrophotometric Determination of Vanadium (V) using 2-Furohydroxamic Acid as A New Analytical Reagent," International Journal of Applied Chemistry, vol. 8, no. 1, pp. 10-12, 2021. Crossref, https://doi.org/10.14445/23939133/IJAC-V8I1P103
Abstract
The new reagent FHA gives a purple-colored complex with Vanadium(V) in an acidic medium. The complex exhibits a wavelength of maximum absorption at 475 nm. The colored system obeys Beer's law in the concentration range of 0.2-16 μg ml–1. The molar absorptivity and Sandell's sensitivity were found to be 2.6 × 104 litre mol–1cm–1 and 0.0136 μgcm–2. The color reaction has been investigated to develop a spectrophotometric method for the determination of Vanadium (V) in an aqueous medium. The reagent has been used for the determination of vanadium in environmental and biological samples.
Keywords
FHA, Vanadium.
References
[1] F.A. Patty, Industrial Hygiene and Toxicology.,Interscience Publisher, New York, 3(1174)(1963).
[2] M. Assefaand, B.S. Chandravanshi, Miko. Chem. Acta,1(1983)(3-4) 255.
[3] A. K. Shrivastava, Int. J. Environ Anal. Chem.,1(27)(1986).
[4] C.L. Chakrabarti, R. J. Magee and C.L. Wilson, Talanta, 34(402) (1968).
[5] U. Priyadarshini and S.G. Tandon, Analyst, 86(1961) 544.
[6] A. Sao, A. Pillai and V. K. Gupta, J. Indian Chem. Soc., 83(400), (2006).
[7] D.E. Ryan, Analyst, 85(1960) 569.
[8] Z. Marczenko, Spectrophotometric Determination of Elements, Wiley New York, (1976).
[9] Y.K. Agrawal, Anal Lett., 5(1972) 563.
[10] L.C. Sillen, Acta Chem. Scand., 10(1956) 185.
[11] (a) U. Priyadarshini and S.G. Tandon, J. Chem. Engg. Data,12(143) (1967).
(b) S. K. Rajput, Ph.D. Thesis, Pt. Ravishankar Shukla University, Raipur, (1984).